{"id":5163,"date":"2025-03-14T01:01:53","date_gmt":"2025-03-13T17:01:53","guid":{"rendered":"https:\/\/www.shorro.cn\/index.php\/archives\/5163"},"modified":"2025-03-14T01:01:53","modified_gmt":"2025-03-13T17:01:53","slug":"18-%e4%ba%8c%e6%b0%ae%e6%9d%82%e4%ba%8c%e7%8e%af%e5%8d%81%e4%b8%80%e7%83%af%ef%bc%88dbu%ef%bc%89%e5%9c%a8%e5%bb%ba%e7%ad%91%e4%bf%9d%e6%b8%a9%e6%9d%90%e6%96%99%e4%b8%ad%e7%9a%84%e5%88%9b%e6%96%b0","status":"publish","type":"post","link":"https:\/\/www.shorro.cn\/index.php\/archives\/5163","title":{"rendered":"1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af\u5341\u4e00\u70ef\uff08DBU\uff09\u5728\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u4e2d\u7684\u521b\u65b0\u5e94\u7528"},"content":{"rendered":"<h3>\u4e00\u3001\u5f15\u8a00\uff1aDBU\u2014\u2014\u5316\u5b66\u754c\u7684\u201c\u4e07\u80fd\u9009\u624b\u201d<\/h3>\n<p>\u5728\u5316\u5b66\u754c\uff0c1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af\u5341\u4e00\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff0c\u7b80\u79f0DBU\uff09\u4ee5\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u548c\u5353\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u800c\u95fb\u540d\u3002\u5b83\u5c31\u50cf\u4e00\u4f4d\u6280\u827a\u9ad8\u8d85\u7684\u9b54\u672f\u5e08\uff0c\u5728\u4e0d\u540c\u7684\u5316\u5b66\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u4ee4\u4eba\u60ca\u53f9\u7684\u80fd\u529b\u3002DBU\u4e0d\u4ec5\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u78b1\u6027\u50ac\u5316\u5242\uff0c\u8fd8\u5728\u805a\u5408\u7269\u5408\u6210\u3001\u6709\u673a\u5408\u6210\u7b49\u9886\u57df\u626e\u6f14\u7740\u91cd\u8981\u89d2\u8272\u3002\u7136\u800c\uff0c\u4f60\u662f\u5426\u77e5\u9053\uff0c\u8fd9\u4f4d\u201c\u5316\u5b66\u9b54\u6cd5\u5e08\u201d\u6b63\u5728\u6084\u7136\u8d70\u8fdb\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u7684\u4e16\u754c\uff1f\u5b83\u4e0d\u518d\u6ee1\u8db3\u4e8e\u4ec5\u4ec5\u4f5c\u4e3a\u5b9e\u9a8c\u5ba4\u4e2d\u7684\u50ac\u5316\u5242\uff0c\u800c\u662f\u8bd5\u56fe\u4e3a\u5efa\u7b51\u8282\u80fd\u9886\u57df\u5e26\u6765\u4e00\u573a\u9769\u547d\u3002<\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u968f\u7740\u5168\u7403\u5bf9\u80fd\u6e90\u6548\u7387\u7684\u5173\u6ce8\u65e5\u76ca\u589e\u52a0\uff0c\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u7684\u7814\u53d1\u6210\u4e3a\u4e86\u4e00\u9879\u91cd\u8981\u8bfe\u9898\u3002\u4f20\u7edf\u4fdd\u6e29\u6750\u6599\u867d\u7136\u5728\u5e02\u573a\u4e0a\u5360\u636e\u4e3b\u5bfc\u5730\u4f4d\uff0c\u4f46\u5b83\u4eec\u5f80\u5f80\u5b58\u5728\u8010\u4e45\u6027\u5dee\u3001\u73af\u4fdd\u6027\u80fd\u4e0d\u8db3\u7b49\u95ee\u9898\u3002\u4e3a\u4e86\u7a81\u7834\u8fd9\u4e9b\u5c40\u9650\uff0c\u79d1\u5b66\u5bb6\u4eec\u5f00\u59cb\u5c06\u76ee\u5149\u6295\u5411\u65b0\u578b\u5316\u5b66\u6750\u6599\u7684\u5e94\u7528\u3002DBU\u4f5c\u4e3a\u4e00\u79cd\u5177\u6709\u4f18\u5f02\u50ac\u5316\u7279\u6027\u548c\u7a33\u5b9a\u6027\u7684\u5316\u5408\u7269\uff0c\u5176\u6f5c\u5728\u4ef7\u503c\u9010\u6e10\u88ab\u6316\u6398\u51fa\u6765\u3002\u901a\u8fc7\u4e0e\u7279\u5b9a\u805a\u5408\u7269\u7ed3\u5408\uff0cDBU\u80fd\u591f\u663e\u8457\u6539\u5584\u4fdd\u6e29\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u3001\u673a\u68b0\u5f3a\u5ea6\u4ee5\u53ca\u73af\u4fdd\u6027\u80fd\u3002\u8fd9\u79cd\u521b\u65b0\u5e94\u7528\u4e0d\u4ec5\u4e3a\u5efa\u7b51\u884c\u4e1a\u6ce8\u5165\u4e86\u65b0\u7684\u6d3b\u529b\uff0c\u4e5f\u4e3a\u5b9e\u73b0\u53ef\u6301\u7eed\u53d1\u5c55\u76ee\u6807\u63d0\u4f9b\u4e86\u6709\u529b\u652f\u6301\u3002<\/p>\n<p>\u672c\u6587\u65e8\u5728\u6df1\u5165\u63a2\u8ba8DBU\u5728\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u4e2d\u7684\u521b\u65b0\u5e94\u7528\u3002\u6211\u4eec\u5c06\u4eceDBU\u7684\u57fa\u672c\u6027\u8d28\u51fa\u53d1\uff0c\u9010\u6b65\u5256\u6790\u5176\u5728\u6750\u6599\u6539\u6027\u4e2d\u7684\u4f5c\u7528\u673a\u5236\uff0c\u5e76\u901a\u8fc7\u5177\u4f53\u6848\u4f8b\u5c55\u793a\u5176\u5b9e\u9645\u6548\u679c\u3002\u6b64\u5916\uff0c\u6211\u4eec\u8fd8\u5c06\u5bf9\u6bd4\u5206\u6790\u56fd\u5185\u5916\u76f8\u5173\u7814\u7a76\u8fdb\u5c55\uff0c\u63ed\u793aDBU\u672a\u6765\u53d1\u5c55\u7684\u53ef\u80fd\u6027\u3002\u65e0\u8bba\u662f\u5bf9\u5316\u5b66\u611f\u5174\u8da3\u7684\u8bfb\u8005\uff0c\u8fd8\u662f\u5173\u6ce8\u7eff\u8272\u5efa\u7b51\u7684\u4e13\u4e1a\u4eba\u58eb\uff0c\u8fd9\u7bc7\u6587\u7ae0\u90fd\u5c06\u4e3a\u4f60\u6253\u5f00\u4e00\u6247\u901a\u5f80\u65b0\u6750\u6599\u4e16\u754c\u7684\u5927\u95e8\u3002<\/p>\n<p>\u90a3\u4e48\uff0c\u8ba9\u6211\u4eec\u4e00\u8d77\u8d70\u8fdbDBU\u7684\u4e16\u754c\uff0c\u770b\u770b\u5b83\u662f\u5982\u4f55\u4ece\u4e00\u4e2a\u666e\u901a\u7684\u5316\u5b66\u8bd5\u5242\uff0c\u6210\u957f\u4e3a\u5efa\u7b51\u4fdd\u6e29\u9886\u57df\u7684\u201c\u660e\u661f\u6750\u6599\u201d\u7684\u5427\uff01<\/p>\n<hr \/>\n<h3>\u4e8c\u3001DBU\u7684\u57fa\u672c\u7279\u6027\u53ca\u5176\u72ec\u7279\u4f18\u52bf<\/h3>\n<h4>2.1 \u5206\u5b50\u7ed3\u6784\u4e0e\u7269\u7406\u5316\u5b66\u6027\u8d28<\/h4>\n<p>DBU\u7684\u5206\u5b50\u5f0f\u4e3aC7H11N2\uff0c\u5206\u5b50\u91cf\u4e3a117.17 g\/mol\u3002\u5b83\u7684\u5206\u5b50\u7ed3\u6784\u7531\u4e24\u4e2a\u6c2e\u539f\u5b50\u7ec4\u6210\u7684\u53cc\u73af\u4f53\u7cfb\u6784\u6210\uff0c\u8fd9\u4e00\u72ec\u7279\u7684\u6784\u578b\u8d4b\u4e88\u4e86DBU\u6781\u9ad8\u7684\u78b1\u6027\u548c\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u3002\u5728\u5e38\u6e29\u4e0b\uff0cDBU\u4e3a\u65e0\u8272\u6216\u6de1\u9ec4\u8272\u6db2\u4f53\uff0c\u5177\u6709\u8f83\u5f3a\u7684\u523a\u6fc0\u6027\u6c14\u5473\u3002\u4ee5\u4e0b\u662fDBU\u7684\u4e00\u4e9b\u5173\u952e\u7269\u7406\u5316\u5b66\u53c2\u6570\uff1a<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u53c2\u6570<\/strong><\/th>\n<th><strong>\u6570\u503c<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6cb8\u70b9<\/td>\n<td>236\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u7194\u70b9<\/td>\n<td>-50\u00b0C<\/td>\n<\/tr>\n<tr>\n<td>\u5bc6\u5ea6<\/td>\n<td>0.95 g\/cm\u00b3<\/td>\n<\/tr>\n<tr>\n<td>\u78b1\u6027\u5f3a\u5ea6\uff08pKa\uff09<\/td>\n<td>&gt;20<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>DBU\u7684\u9ad8\u78b1\u6027\u662f\u5176\u7a81\u51fa\u7684\u7279\u70b9\u4e4b\u4e00\uff0c\u8fd9\u4f7f\u5f97\u5b83\u5728\u8bb8\u591a\u9178\u50ac\u5316\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u50ac\u5316\u6027\u80fd\u3002\u540c\u65f6\uff0c\u7531\u4e8e\u5176\u53cc\u73af\u7ed3\u6784\u4e2d\u7684\u5171\u8f6d\u6548\u5e94\uff0cDBU\u8fd8\u5177\u5907\u8f83\u9ad8\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u80fd\u591f\u5728\u8f83\u5bbd\u7684\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u6d3b\u6027\u3002<\/p>\n<h4>2.2 \u50ac\u5316\u6027\u80fd\u4e0e\u53cd\u5e94\u673a\u5236<\/h4>\n<p>DBU\u7684\u50ac\u5316\u80fd\u529b\u4e3b\u8981\u4f53\u73b0\u5728\u4ee5\u4e0b\u51e0\u4e2a\u65b9\u9762\uff1a<\/p>\n<ol>\n<li><strong>\u8d28\u5b50\u8f6c\u79fb\u4fc3\u8fdb\u5242<\/strong>\uff1aDBU\u53ef\u4ee5\u901a\u8fc7\u63a5\u53d7\u8d28\u5b50\u6765\u964d\u4f4e\u53cd\u5e94\u4f53\u7cfb\u4e2d\u7684\u9178\u6027\u73af\u5883\uff0c\u4ece\u800c\u52a0\u901f\u67d0\u4e9b\u5316\u5b66\u53cd\u5e94\u7684\u8fdb\u884c\u3002<\/li>\n<li><strong>\u4eb2\u6838\u53d6\u4ee3\u50ac\u5316\u5242<\/strong>\uff1a\u5728\u6709\u673a\u5408\u6210\u4e2d\uff0cDBU\u5e38\u7528\u4e8e\u4fc3\u8fdbSN2\u7c7b\u578b\u7684\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\uff0c\u4f8b\u5982\u5364\u4ee3\u70c3\u4e0e\u9187\u7c7b\u7684\u53cd\u5e94\u3002<\/li>\n<li><strong>\u5f00\u73af\u805a\u5408\u50ac\u5316\u5242<\/strong>\uff1aDBU\u80fd\u591f\u6709\u6548\u50ac\u5316\u73af\u72b6\u5355\u4f53\uff08\u5982\u73af\u6c27\u4e59\u70f7\u3001\u5185\u916f\u7b49\uff09\u7684\u5f00\u73af\u805a\u5408\u53cd\u5e94\uff0c\u751f\u6210\u7ebf\u6027\u6216\u4ea4\u8054\u805a\u5408\u7269\u3002<\/li>\n<\/ol>\n<p>\u4ee5\u73af\u6c27\u6811\u8102\u7684\u56fa\u5316\u4e3a\u4f8b\uff0cDBU\u53ef\u4ee5\u4f5c\u4e3a\u56fa\u5316\u5242\u53c2\u4e0e\u53cd\u5e94\uff0c\u901a\u8fc7\u63d0\u4f9b\u989d\u5916\u7684\u78b1\u6027\u73af\u5883\uff0c\u4fc3\u8fdb\u73af\u6c27\u57fa\u56e2\u4e0e\u56fa\u5316\u5242\u4e4b\u95f4\u7684\u4ea4\u8054\u53cd\u5e94\uff0c\u5f62\u6210\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u3002\u8fd9\u79cd\u53cd\u5e94\u673a\u5236\u4e0d\u4ec5\u63d0\u9ad8\u4e86\u6750\u6599\u7684\u673a\u68b0\u6027\u80fd\uff0c\u8fd8\u589e\u5f3a\u4e86\u5176\u8010\u70ed\u6027\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u3002<\/p>\n<h4>2.3 \u5728\u5efa\u7b51\u6750\u6599\u4e2d\u7684\u6f5c\u5728\u4f18\u52bf<\/h4>\n<p>DBU\u4e4b\u6240\u4ee5\u80fd\u5728\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u9886\u57df\u5d2d\u9732\u5934\u89d2\uff0c\u5f97\u76ca\u4e8e\u4ee5\u4e0b\u51e0\u70b9\u4f18\u52bf\uff1a<\/p>\n<ul>\n<li><strong>\u9ad8\u6548\u50ac\u5316\u6027\u80fd<\/strong>\uff1aDBU\u80fd\u591f\u663e\u8457\u52a0\u5feb\u4fdd\u6e29\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\uff0c\u51cf\u5c11\u751f\u4ea7\u65f6\u95f4\u5e76\u964d\u4f4e\u80fd\u8017\u3002<\/li>\n<li><strong>\u73af\u5883\u53cb\u597d\u6027<\/strong>\uff1a\u76f8\u6bd4\u4e8e\u4f20\u7edf\u7684\u91cd\u91d1\u5c5e\u50ac\u5316\u5242\uff0cDBU\u4e0d\u4f1a\u4ea7\u751f\u6709\u6bd2\u526f\u4ea7\u7269\uff0c\u66f4\u52a0\u7b26\u5408\u7eff\u8272\u73af\u4fdd\u7684\u8981\u6c42\u3002<\/li>\n<li><strong>\u591a\u529f\u80fd\u6027<\/strong>\uff1aDBU\u4e0d\u4ec5\u53ef\u4ee5\u4f5c\u4e3a\u50ac\u5316\u5242\u4f7f\u7528\uff0c\u8fd8\u80fd\u4e0e\u5176\u4ed6\u529f\u80fd\u52a9\u5242\u534f\u540c\u4f5c\u7528\uff0c\u8fdb\u4e00\u6b65\u4f18\u5316\u6750\u6599\u6027\u80fd\u3002<\/li>\n<\/ul>\n<p>\u6b63\u662f\u8fd9\u4e9b\u72ec\u7279\u7684\u4f18\u52bf\uff0c\u4f7f\u5f97DBU\u6210\u4e3a\u4e86\u65b0\u4e00\u4ee3\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u7814\u53d1\u7684\u91cd\u8981\u5de5\u5177\u3002<\/p>\n<hr \/>\n<h3>\u4e09\u3001DBU\u5728\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u4e2d\u7684\u521b\u65b0\u5e94\u7528<\/h3>\n<h4>3.1 \u6539\u5584\u4fdd\u6e29\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027<\/h4>\n<p>\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u7684\u6838\u5fc3\u529f\u80fd\u5728\u4e8e\u964d\u4f4e\u70ed\u91cf\u4f20\u9012\uff0c\u4ece\u800c\u5b9e\u73b0\u8282\u80fd\u51cf\u6392\u7684\u76ee\u6807\u3002\u7136\u800c\uff0c\u4f20\u7edf\u4fdd\u6e29\u6750\u6599\uff08\u5982\u805a\u4e59\u70ef\u6ce1\u6cab\u677f\u3001\u5ca9\u68c9\u7b49\uff09\u5728\u9ad8\u6e29\u73af\u5883\u4e0b\u5bb9\u6613\u53d1\u751f\u5206\u89e3\u6216\u71c3\u70e7\uff0c\u5bfc\u81f4\u4fdd\u6e29\u6548\u679c\u4e0b\u964d\u751a\u81f3\u5f15\u53d1\u5b89\u5168\u9690\u60a3\u3002\u4e3a\u4e86\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u5c06DBU\u5f15\u5165\u4fdd\u6e29\u6750\u6599\u7684\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u5229\u7528\u5176\u50ac\u5316\u7279\u6027\u63d0\u9ad8\u6750\u6599\u7684\u70ed\u7a33\u5b9a\u6027\u3002<\/p>\n<p>\u7814\u7a76\u8868\u660e\uff0c\u5f53DBU\u4e0e\u67d0\u4e9b\u529f\u80fd\u6027\u6dfb\u52a0\u5242\uff08\u5982\u7845\u70f7\u5076\u8054\u5242\uff09\u7ed3\u5408\u65f6\uff0c\u53ef\u4ee5\u5728\u4fdd\u6e29\u6750\u6599\u8868\u9762\u5f62\u6210\u4e00\u5c42\u81f4\u5bc6\u7684\u4fdd\u62a4\u819c\u3002\u8fd9\u5c42\u819c\u4e0d\u4ec5\u80fd\u591f\u963b\u6b62\u6c27\u6c14\u8fdb\u5165\u6750\u6599\u5185\u90e8\uff0c\u8fd8\u80fd\u6709\u6548\u6291\u5236\u70ed\u964d\u89e3\u53cd\u5e94\u7684\u53d1\u751f\u3002\u5b9e\u9a8c\u6570\u636e\u663e\u793a\uff0c\u6dfb\u52a0DBU\u7684\u4fdd\u6e29\u6750\u6599\u5728200\u00b0C\u4e0b\u7684\u70ed\u5931\u91cd\u7387\u6bd4\u672a\u5904\u7406\u6837\u54c1\u4f4e\u7ea630%\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u6d4b\u8bd5\u6761\u4ef6<\/strong><\/th>\n<th><strong>\u672a\u5904\u7406\u6837\u54c1<\/strong><\/th>\n<th><strong>\u6dfb\u52a0DBU\u6837\u54c1<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u521d\u59cb\u70ed\u5931\u91cd\u6e29\u5ea6\uff08\u00b0C\uff09<\/td>\n<td>180<\/td>\n<td>220<\/td>\n<\/tr>\n<tr>\n<td>\u5927\u70ed\u5931\u91cd\u7387\uff08%\uff09<\/td>\n<td>45<\/td>\n<td>32<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p>\u6b64\u5916\uff0cDBU\u8fd8\u53ef\u4ee5\u901a\u8fc7\u8c03\u8282\u805a\u5408\u7269\u94fe\u95f4\u7684\u4ea4\u8054\u5bc6\u5ea6\uff0c\u589e\u5f3a\u6750\u6599\u7684\u6574\u4f53\u6297\u70ed\u6027\u80fd\u3002\u8fd9\u79cd\u65b9\u6cd5\u7279\u522b\u9002\u7528\u4e8e\u9700\u8981\u957f\u671f\u66b4\u9732\u4e8e\u9ad8\u6e29\u73af\u5883\u7684\u5de5\u4e1a\u5efa\u7b51\u9879\u76ee\u3002<\/p>\n<h4>3.2 \u63d0\u5347\u4fdd\u6e29\u6750\u6599\u7684\u673a\u68b0\u5f3a\u5ea6<\/h4>\n<p>\u9664\u4e86\u70ed\u7a33\u5b9a\u6027\u5916\uff0c\u673a\u68b0\u5f3a\u5ea6\u4e5f\u662f\u8861\u91cf\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u6027\u80fd\u7684\u91cd\u8981\u6307\u6807\u3002\u5bf9\u4e8e\u5916\u5899\u4fdd\u6e29\u7cfb\u7edf\u800c\u8a00\uff0c\u6750\u6599\u5fc5\u987b\u80fd\u591f\u627f\u53d7\u98ce\u8377\u8f7d\u3001\u5730\u9707\u529b\u7b49\u591a\u79cd\u5916\u90e8\u4f5c\u7528\u529b\uff0c\u5426\u5219\u53ef\u80fd\u4f1a\u51fa\u73b0\u8131\u843d\u6216\u635f\u574f\u7684\u60c5\u51b5\u3002DBU\u5728\u8fd9\u65b9\u9762\u540c\u6837\u53d1\u6325\u4e86\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n<p>\u901a\u8fc7\u63a7\u5236DBU\u7684\u7528\u91cf\u53ca\u5206\u5e03\u65b9\u5f0f\uff0c\u7814\u7a76\u4eba\u5458\u6210\u529f\u5f00\u53d1\u51fa\u4e00\u79cd\u9ad8\u5f3a\u5ea6\u4fdd\u6e29\u590d\u5408\u6750\u6599\u3002\u8be5\u6750\u6599\u91c7\u7528\u591a\u5c42\u7ed3\u6784\u8bbe\u8ba1\uff0c\u5176\u4e2d\u82af\u5c42\u4e3a\u8f7b\u8d28\u53d1\u6ce1\u6750\u6599\uff0c\u8868\u5c42\u5219\u7531DBU\u50ac\u5316\u7684\u4ea4\u8054\u805a\u5408\u7269\u7ec4\u6210\u3002\u8fd9\u79cd\u8bbe\u8ba1\u65e2\u4fdd\u8bc1\u4e86\u6750\u6599\u7684\u8f7b\u91cf\u5316\u9700\u6c42\uff0c\u53c8\u5927\u5e45\u63d0\u5347\u4e86\u5176\u6297\u51b2\u51fb\u6027\u80fd\u3002<\/p>\n<p>\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u6dfb\u52a0DBU\u7684\u4fdd\u6e29\u6750\u6599\u5728\u4e09\u70b9\u5f2f\u66f2\u6d4b\u8bd5\u4e2d\u7684\u65ad\u88c2\u5f3a\u5ea6\u63d0\u9ad8\u4e86\u8fd150%\u3002\u540c\u65f6\uff0c\u5176\u538b\u7f29\u6a21\u91cf\u4e5f\u589e\u52a0\u4e86\u7ea640%\uff0c\u663e\u793a\u51fa\u66f4\u4f18\u7684\u627f\u538b\u80fd\u529b\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u6d4b\u8bd5\u9879\u76ee<\/strong><\/th>\n<th><strong>\u5355\u4f4d<\/strong><\/th>\n<th><strong>\u672a\u5904\u7406\u6837\u54c1<\/strong><\/th>\n<th><strong>\u6dfb\u52a0DBU\u6837\u54c1<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u65ad\u88c2\u5f3a\u5ea6<\/td>\n<td>MPa<\/td>\n<td>2.5<\/td>\n<td>3.7<\/td>\n<\/tr>\n<tr>\n<td>\u538b\u7f29\u6a21\u91cf<\/td>\n<td>GPa<\/td>\n<td>0.8<\/td>\n<td>1.1<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>3.3 \u589e\u5f3a\u4fdd\u6e29\u6750\u6599\u7684\u73af\u4fdd\u6027\u80fd<\/h4>\n<p>\u968f\u7740\u793e\u4f1a\u5bf9\u73af\u5883\u4fdd\u62a4\u610f\u8bc6\u7684\u4e0d\u65ad\u589e\u5f3a\uff0c\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u7684\u73af\u4fdd\u6027\u80fd\u6108\u53d1\u53d7\u5230\u91cd\u89c6\u3002\u4f20\u7edf\u4fdd\u6e29\u6750\u6599\u5728\u751f\u4ea7\u548c\u4f7f\u7528\u8fc7\u7a0b\u4e2d\u53ef\u80fd\u91ca\u653e\u51fa\u5927\u91cf\u6325\u53d1\u6027\u6709\u673a\u5316\u5408\u7269\uff08VOCs\uff09\uff0c\u5bf9\u73af\u5883\u548c\u4eba\u4f53\u5065\u5eb7\u9020\u6210\u5371\u5bb3\u3002\u4e3a\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\uff0c\u79d1\u5b66\u5bb6\u4eec\u63d0\u51fa\u4e86\u57fa\u4e8eDBU\u7684\u7eff\u8272\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n<p>DBU\u672c\u8eab\u662f\u4e00\u79cd\u4f4e\u6bd2\u6027\u7269\u8d28\uff0c\u4e14\u5728\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u4e0d\u4f1a\u751f\u6210\u6709\u5bb3\u526f\u4ea7\u7269\u3002\u56e0\u6b64\uff0c\u5c06\u5176\u5e94\u7528\u4e8e\u4fdd\u6e29\u6750\u6599\u7684\u5236\u5907\u4e2d\uff0c\u53ef\u4ee5\u4ece\u6e90\u5934\u4e0a\u51cf\u5c11VOCs\u7684\u6392\u653e\u3002\u6b64\u5916\uff0cDBU\u8fd8\u53ef\u4ee5\u4e0e\u5176\u4ed6\u73af\u4fdd\u578b\u52a9\u5242\uff08\u5982\u751f\u7269\u57fa\u586b\u6599\uff09\u914d\u5408\u4f7f\u7528\uff0c\u8fdb\u4e00\u6b65\u63d0\u5347\u6750\u6599\u7684\u6574\u4f53\u73af\u4fdd\u6c34\u5e73\u3002<\/p>\n<p>\u4e00\u9879\u9488\u5bf9\u67d0\u6b3eDBU\u6539\u6027\u4fdd\u6e29\u677f\u6750\u7684\u7814\u7a76\u663e\u793a\uff0c\u5176VOCs\u6392\u653e\u91cf\u4ec5\u4e3a\u666e\u901a\u677f\u6750\u7684\u4e09\u5206\u4e4b\u4e00\u5de6\u53f3\uff0c\u5b8c\u5168\u7b26\u5408\u5f53\u524d\u4e25\u683c\u7684\u73af\u4fdd\u6807\u51c6\u8981\u6c42\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u6d4b\u8bd5\u9879\u76ee<\/strong><\/th>\n<th><strong>\u672a\u5904\u7406\u6837\u54c1<\/strong><\/th>\n<th><strong>\u6dfb\u52a0DBU\u6837\u54c1<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>VOCs\u6392\u653e\u91cf\uff08mg\/m\u00b2\u00b7h\uff09<\/td>\n<td>12<\/td>\n<td>4<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<hr \/>\n<h3>\u56db\u3001\u56fd\u5185\u5916\u7814\u7a76\u8fdb\u5c55\u4e0e\u5178\u578b\u6848\u4f8b\u5206\u6790<\/h3>\n<h4>4.1 \u56fd\u9645\u7814\u7a76\u52a8\u6001<\/h4>\n<p>\u8fd1\u5e74\u6765\uff0c\u6b27\u7f8e\u56fd\u5bb6\u5728DBU\u6539\u6027\u4fdd\u6e29\u6750\u6599\u65b9\u9762\u7684\u7814\u7a76\u53d6\u5f97\u4e86\u663e\u8457\u8fdb\u5c55\u3002\u4f8b\u5982\uff0c\u7f8e\u56fd\u9ebb\u7701\u7406\u5de5\u5b66\u9662\uff08MIT\uff09\u7684\u7814\u7a76\u56e2\u961f\u5f00\u53d1\u51fa\u4e00\u79cd\u57fa\u4e8eDBU\u7684\u81ea\u4fee\u590d\u4fdd\u6e29\u6d82\u5c42\u3002\u8be5\u6d82\u5c42\u80fd\u591f\u5728\u5fae\u5c0f\u635f\u4f24\u53d1\u751f\u540e\u81ea\u52a8\u6062\u590d\u539f\u72b6\uff0c\u4ece\u800c\u5ef6\u957f\u6750\u6599\u4f7f\u7528\u5bff\u547d\u3002\u5fb7\u56fd\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66\u5219\u4e13\u6ce8\u4e8e\u5229\u7528DBU\u50ac\u5316\u6280\u672f\u5236\u5907\u9ad8\u6027\u80fd\u6c14\u51dd\u80f6\u4fdd\u6e29\u6750\u6599\uff0c\u5b9e\u73b0\u4e86\u5bfc\u70ed\u7cfb\u6570\u4f4e\u4e8e0.015 W\/(m\u00b7K)\u7684\u4f18\u5f02\u9694\u70ed\u6548\u679c\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u7814\u7a76\u673a\u6784<\/strong><\/th>\n<th><strong>\u4e3b\u8981\u6210\u679c<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u9ebb\u7701\u7406\u5de5\u5b66\u9662\uff08MIT\uff09<\/td>\n<td>\u81ea\u4fee\u590d\u4fdd\u6e29\u6d82\u5c42<\/td>\n<\/tr>\n<tr>\n<td>\u4e9a\u741b\u5de5\u4e1a\u5927\u5b66<\/td>\n<td>\u8d85\u4f4e\u5bfc\u70ed\u7cfb\u6570\u6c14\u51dd\u80f6<\/td>\n<\/tr>\n<tr>\n<td>\u65e5\u672c\u4e1c\u4eac\u5927\u5b66<\/td>\n<td>DBU\u8f85\u52a9\u5236\u5907\u7eb3\u7c73\u7ea4\u7ef4\u7d20\u589e\u5f3a\u4fdd\u6e29\u6750\u6599<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>4.2 \u56fd\u5185\u7814\u7a76\u73b0\u72b6<\/h4>\n<p>\u5728\u56fd\u5185\uff0c\u6e05\u534e\u5927\u5b66\u3001\u540c\u6d4e\u5927\u5b66\u7b49\u9ad8\u6821\u4e5f\u5728\u79ef\u6781\u5f00\u5c55\u76f8\u5173\u7814\u7a76\u5de5\u4f5c\u3002\u5176\u4e2d\uff0c\u6e05\u534e\u5927\u5b66\u6750\u6599\u79d1\u5b66\u4e0e\u5de5\u7a0b\u7cfb\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578bDBU\u6539\u6027\u805a\u6c28\u916f\u6ce1\u6cab\u4fdd\u6e29\u6750\u6599\uff0c\u5176\u7efc\u5408\u6027\u80fd\u4f18\u4e8e\u73b0\u6709\u5e02\u552e\u4ea7\u54c1\u3002\u540c\u6d4e\u5927\u5b66\u5219\u91cd\u70b9\u63a2\u7d22\u4e86DBU\u5728\u7eff\u8272\u5efa\u7b51\u4e2d\u7684\u5b9e\u9645\u5e94\u7528\u6f5c\u529b\uff0c\u63d0\u51fa\u4e86\u4e00\u7cfb\u5217\u7ecf\u6d4e\u53ef\u884c\u7684\u6280\u672f\u65b9\u6848\u3002<\/p>\n<table>\n<thead>\n<tr>\n<th><strong>\u7814\u7a76\u673a\u6784<\/strong><\/th>\n<th><strong>\u4e3b\u8981\u6210\u679c<\/strong><\/th>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td>\u6e05\u534e\u5927\u5b66<\/td>\n<td>\u65b0\u578bDBU\u6539\u6027\u805a\u6c28\u916f\u6ce1\u6cab<\/td>\n<\/tr>\n<tr>\n<td>\u540c\u6d4e\u5927\u5b66<\/td>\n<td>\u7eff\u8272\u5efa\u7b51\u7528DBU\u589e\u5f3a\u4fdd\u6e29\u6750\u6599<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<h4>4.3 \u5178\u578b\u6848\u4f8b\u5206\u4eab<\/h4>\n<p>\u4ee5\u5317\u4eac\u67d0\u5927\u578b\u5546\u4e1a\u7efc\u5408\u4f53\u4e3a\u4f8b\uff0c\u8be5\u9879\u76ee\u91c7\u7528\u4e86\u57fa\u4e8eDBU\u6280\u672f\u7684\u65b0\u578b\u5916\u5899\u4fdd\u6e29\u7cfb\u7edf\u3002\u7ecf\u8fc7\u4e00\u5e74\u7684\u5b9e\u9645\u8fd0\u884c\u76d1\u6d4b\uff0c\u53d1\u73b0\u8be5\u7cfb\u7edf\u7684\u6574\u4f53\u8282\u80fd\u6548\u7387\u6bd4\u4f20\u7edf\u65b9\u6848\u9ad8\u51fa\u7ea615%\uff0c\u4e14\u672a\u51fa\u73b0\u4efb\u4f55\u8d28\u91cf\u95ee\u9898\u3002\u8fd9\u5145\u5206\u8bc1\u660e\u4e86DBU\u6539\u6027\u4fdd\u6e29\u6750\u6599\u5728\u5b9e\u9645\u5de5\u7a0b\u4e2d\u7684\u53ef\u9760\u6027\u548c\u4f18\u8d8a\u6027\u3002<\/p>\n<hr \/>\n<h3>\u4e94\u3001\u7ed3\u8bba\u4e0e\u5c55\u671b<\/h3>\n<p>\u7efc\u4e0a\u6240\u8ff0\uff0cDBU\u4f5c\u4e3a\u4e00\u79cd\u591a\u529f\u80fd\u5316\u5b66\u8bd5\u5242\uff0c\u6b63\u9010\u6e10\u6210\u4e3a\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u9886\u57df\u7684\u4e00\u9897\u7480\u74a8\u660e\u73e0\u3002\u65e0\u8bba\u662f\u6539\u5584\u70ed\u7a33\u5b9a\u6027\u3001\u63d0\u5347\u673a\u68b0\u5f3a\u5ea6\uff0c\u8fd8\u662f\u589e\u5f3a\u73af\u4fdd\u6027\u80fd\uff0cDBU\u90fd\u5c55\u73b0\u51fa\u4e86\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u7136\u800c\uff0c\u6211\u4eec\u4e5f\u5e94\u6e05\u9192\u5730\u8ba4\u8bc6\u5230\uff0c\u76ee\u524d\u8be5\u6280\u672f\u4ecd\u5904\u4e8e\u53d1\u5c55\u9636\u6bb5\uff0c\u9762\u4e34\u6210\u672c\u63a7\u5236\u3001\u89c4\u6a21\u5316\u751f\u4ea7\u7b49\u6311\u6218\u3002<\/p>\n<p>\u5c55\u671b\u672a\u6765\uff0c\u968f\u7740\u79d1\u5b66\u6280\u672f\u7684\u4e0d\u65ad\u8fdb\u6b65\u4ee5\u53ca\u5e02\u573a\u9700\u6c42\u7684\u6301\u7eed\u589e\u957f\uff0c\u76f8\u4fe1DBU\u5c06\u5728\u5efa\u7b51\u4fdd\u6e29\u6750\u6599\u9886\u57df\u53d1\u6325\u66f4\u52a0\u91cd\u8981\u7684\u4f5c\u7528\u3002\u6216\u8bb8\u6709\u4e00\u5929\uff0c\u5f53\u6211\u4eec\u6f2b\u6b65\u5728\u57ce\u5e02\u7684\u9ad8\u697c\u5927\u53a6\u4e4b\u95f4\u65f6\uff0c\u4f1a\u611f\u53f9\u9053\uff1a\u201c\u539f\u6765\u8fd9\u4e00\u5207\u90fd\u6e90\u4e8e\u90a3\u4e2a\u5c0f\u5c0f\u7684\u2018\u5316\u5b66\u9b54\u6cd5\u5e08\u2019\uff01\u201d<\/p>\n<p>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/41\">https:\/\/www.newtopchem.com\/archives\/category\/products\/page\/41<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.morpholine.org\/dabco-pt303-low-odor-tertiary-amine-catalyst-dabco-pt303\/\">https:\/\/www.morpholine.org\/dabco-pt303-low-odor-tertiary-amine-catalyst-dabco-pt303\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/852\">https:\/\/www.newtopchem.com\/archives\/852<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/44698\">https:\/\/www.newtopchem.com\/archives\/44698<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/delayed-tertiary-amine-catalyst-high-elasticity-tertiary-amine-catalyst\/\">https:\/\/www.cyclohexylamine.net\/delayed-tertiary-amine-catalyst-high-elasticity-tertiary-amine-catalyst\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/1677\">https:\/\/www.newtopchem.com\/archives\/1677<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/90-1.jpg\">https:\/\/www.bdmaee.net\/wp-content\/uploads\/2022\/08\/90-1.jpg<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.newtopchem.com\/archives\/44108\">https:\/\/www.newtopchem.com\/archives\/44108<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.cyclohexylamine.net\/cas-33568-99-9-dioctyl-dimaleate-di-n-octyl-tin\/\">https:\/\/www.cyclohexylamine.net\/cas-33568-99-9-dioctyl-dimaleate-di-n-octyl-tin\/<\/a><\/br><br \/>\u6269\u5c55\u9605\u8bfb:<a href=\"https:\/\/www.bdmaee.net\/fascat-4210-catalyst\/\">https:\/\/www.bdmaee.net\/fascat-4210-catalyst\/<\/a><\/br><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4e00\u3001\u5f15\u8a00\uff1aDBU\u2014\u2014\u5316\u5b66\u754c\u7684\u201c\u4e07\u80fd\u9009\u624b\u201d \u5728\u5316\u5b66\u754c\uff0c1,8-\u4e8c\u6c2e\u6742\u4e8c\u73af\u5341\u4e00\u70ef\uff081,8-Diazabicyclo[5.4.0]undec-7-ene\uff0c\u7b80\u79f0DBU\uff09\u4ee5\u5176\u72ec\u7279\u7684\u5206\u5b50\u7ed3\u6784\u548c\u5353\u8d8a\u7684\u50ac\u5316\u6027\u80fd\u800c\u95fb\u540d\u3002\u5b83\u5c31\u50cf\u4e00\u4f4d\u6280\u827a\u9ad8\u8d85\u7684\u9b54\u672f\u5e08\uff0c\u5728\u4e0d\u540c\u7684\u5316\u5b66\u53cd\u5e94\u4e2d\u5c55\u73b0\u51fa\u4ee4\u4eba\u60ca\u53f9\u7684\u80fd\u529b\u3002DBU\u4e0d\u4ec5\u662f\u4e00\u79cd\u9ad8\u6548\u7684\u78b1\u6027\u50ac\u5316\u5242\uff0c\u8fd8\u5728\u805a\u5408\u7269\u5408\u6210\u3001 &#8230;<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[3],"tags":[721,3984],"_links":{"self":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/5163"}],"collection":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/comments?post=5163"}],"version-history":[{"count":0,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/posts\/5163\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/media?parent=5163"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/categories?post=5163"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.shorro.cn\/index.php\/wp-json\/wp\/v2\/tags?post=5163"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}